Abstract
High-resolution Fourier transform infrared spectra of natural trans-ClHC CHF and of its isotopologue trans-ClHC CDF have been recorded in the region between 700 and 1150 cm −1 with the purpose to analyze the ν 11 fundamental of the main species and the ν 10 of its deuterated compound. Both bands, of symmetry species A″, present c-type envelope absorptions. Beside the expected features, the K structure of the P( J), Q( J), and R( J) manifolds was resolved and identified; the assignment of the rovibrational transitions was extended up to J = 92 and K a = 13 for the trans- 35ClHC CHF and up to J = 86 and K a = 10 for trans- 35ClHC CDF. More than 2900 and 2700 lines for the main and deuterated species, respectively, were analyzed by a least-squares procedure and reliable spectroscopic molecular parameters were determined for both isotopologues.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
