FT-ICR study on hydrogenation of niobium cluster cations Nbn+ (n=2–15) in seeded supersonic jet and multiple-collision-induced dissociation of NbnHm+ hydrides

Abstract

Hydrogenation of niobium cluster cations Nbn+ (n=2–15) in a seeded supersonic jet of H2/He and multiple-collision-induced dissociation (MCID) of the resulting NbnHm+ hydrides have been studied using a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The nascent NbnHm+ hydrides trapped in the FT-ICR cell have broad m distributions with no apparent prevalence of odd or even m. A pulse of argon applied to the trapped clusters causes a dramatic squeezing of the initial m distribution (through the collision-induced removal of weakly bound H2 molecules), favoring several particular hydrides for each cluster size n, e.g., Nb7H8+, Nb7H11+, and Nb7H12+ for n=7. The maximum m values of these stable hydrides are close to the stoichiometric composition of NbH2 for the clusters with n<13, and approach that of NbH at larger n. The hydrides observed in our experiments are different from the products of the Nbn++H2 reactions performed in the FT-ICR cell at room temperature, which show only even and strongly n-dependent m values. The MCID of the NbnHm+ clusters occurs through the sequential desorption of H2 molecules yielding NbnH+ and Nbn+ as final dissociation products for odd and even m, respectively. Based on the experiments on the MCID of Nb12H18+, an explanation is suggested for different reactivities of the Nb12+ clusters toward H2 in the ICR and fast-flow-reactor experiments.