Abstract
This study reports on mineral and bulk rock compositions of metaperidotites from the Alag Khadny accretionary complex in SW Mongolia, to reveal their nature and relationships with associated eclogites. The peridotites preserved original porphyroclastic textures and are composed of olivine, orthopyroxene relics, Cr-spinel, interstitial (not residual) clinopyroxene, and secondary chlorite, tremolite, olivine, Cr-magnetite, clinopyroxene, and antigorite. Cr-spinel has Cr# of 0.3–0.5, and primary olivine shows Mg# of 0.90–0.92. The pyroxenes are high-magnesian with low Al2O3 and Cr2O3. The bulk rocks have U-shaped normalized trace-element patterns with enrichment in LILE, L-MREE relative to HREE, and weak Pb–Sr peaks and Nb–Zr–Hf minima. Interstitial clinopyroxene exhibits V- and U-shaped normalized REE patterns with (La/Yb)N > 1 (Yb = 1.2–3 of chondritic values) and enrichment in fluid-mobile elements and Zr. HREE abundances of clinopyroxene can be simulated by 23–26% partial melting of depleted mantle starting at garnet-facies (6–8%) depths, followed by hydrous or anhydrous melting at spinel-facies depths L-MREE characteristics of clinopyroxenes can be simulated by further interaction of harzburgites with an island-arc basaltic melt in a supra-subduction environment. The association of hydrous secondary minerals in the Alag Khadny peridotites suggests their retrograde metamorphism at 1.6–2.0 GPa and 640–720 °C, similar to P–T conditions reported earlier for the spatially associated eclogites. This supports metamorphism of the Alag Khadny peridotites in a mantle wedge, followed by joint exhumation of peridotites and eclogites. Given the findings above and implying the regional geological background, we advocate for a sequential Neoproterozoic evolution the Alag Khadny harzburgites from (1) their formation by decompression partial melting in an Early Neoproterozoic or older spreading center of a mid-ocean or back-arc setting, and (2) refertilization by supra-subduction melts, followed by (3) Late Neoproterozoic–Early Cambrian hydrous-fluid metamorphism and juxtaposition with eclogites.
Highlights
Serpentinized peridotites are crucial for recycling of volatiles and fluid-mobile elements (FME) in subduction zones [1,2,3,4]
Abundances of major (Figure 5) and the least incompatible elements (HREE and Ti) (Figure 6) in Abundances of major (Figure 5) and the least incompatible elements (HREE and Ti) (Figure 6) in the the studied rocks point to residual nature of the Alag Khadny peridotites
In the Alag Khadny harzburgites, Cpx1 crystallized from percolating incremental or aggregated melts generated in the mantle column at deeper levels, immediately after final stages of melting
Summary
Serpentinized peridotites are crucial for recycling of volatiles and fluid-mobile elements (FME) in subduction zones [1,2,3,4]. Peridotites of a mantle wedge witnessed various petrologic processes such as metamorphism [12,13], modification by subduction fluids [14], and upward migration of supra-subduction zone (SSZ) melts [15,16]. Minerals 2020, 10, 396 and chemical compositions, as well as associated rock types, depending on nature of subducting lithosphere, i.e., oceanic or continental [17]. It was demonstrated multiple times that the presence of serpentinized peridotites may facilitate processes of exhumation of high-pressure (HP) rock, such as eclogites and blueschists [9,19,20]. A new Neoproterozoic–Early Cambrian Alag Khadny (AK) high-pressure assemblage of eclogites, metasediments and metagranitoids (40 Ar–39 Ar, phengite, 537–548 Ma) [21,22,23] was recognized in the
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