Abstract
This paper describes first the free radical quaterpolymerization of acceptor-monomers (maleic anhydride (MSA), fumaronitrile (FN) and N-ethylmaleimide (NEMI)) and donor-monomers (trans-anethole (ANE), Vinyl-iso-butylether (VIBE), trans-stilbene (Stb) and 2-chloroethyl vinylether (CEVE)). They form quaternary Systems from two acceptors and two donors (MSA/FN/ANE/VIBE) as well as from one acceptor and three donors (NEMI/ANE/Stb/CEVE and MSA/ANE/Stb/CEVE). A first time presented quaterpolymerization diagram can describe the relationship between the polymer composition and the monomer feed. The relative reactivities of these monomers were determined. Against the common acceptor macroradical the donor monomer ANE is more reactive than VIBE, Stb and CEVE.
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