Abstract
Abstract Framework structures of ternary metal chalcogenides with tetrahedral and planar coordination of transition metal atoms are discussed by using an extended Zintl principle. Their bonding can be characterized by the magnetic moments measured by neutron diffraction. The experimental results are compared with crystal field splittings obtained by calculations based on the strong field model. This is an attempt to explain the occurrence of reduced spin states of transition metal atoms in tetrahedral coordination in terms of a dependence on the framework structure.
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