Abstract
Wurtzite (W)-type ZnO condensates showed preferred orientation { 1 0 1 ¯ 1 } when deposited on glass substrate by pulse laser ablation on Zn target in the presence of oxygen. Such an artificial epitaxy depends on the well-developed { 1 0 1 ¯ 1 } surfaces of the condensates, which enabled { 1 0 1 ¯ 1 } -specific coalescence to form twin and single crystal regardless of the co-deposited Zn. The W-ZnO condensates have decreasing particle size with increasing oxygen flow rate and a considerable residual stress due to the combined effects of rapid heating/cooling and thermal/lattice mismatch with Zn following parallel epitaxy or ( 0 1 1 ¯ 1 ¯ ) W-ZnO / / ( 0 1 1 ¯ 0 ) Zn ; [ 1 ¯ 2 1 ¯ 3 ] W-ZnO / / [ 0 0 0 1 ] Zn involving { 1 0 1 ¯ 1 } slip.
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