Abstract
Two nitrogen-doped positively curved aromatic molecules bearing doubly fused pentagonal rings were synthesized and characterized. Crystallographic analysis confirms the formation of a bowl-shaped structure, which is induced by the fusion of adjacent pentagons to the rigid aromatic planes. Both compounds demonstrate good photoluminescence. These electron-rich bowl-shaped molecules can associate with C60 to form complexes in 2:1 ratio in toluene with different association constants depending on the molecular dimension of the hosts.
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