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https://doi.org/10.1016/s0020-1693(00)86054-5
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Cite Journal: Inorganica Chimica Acta |  Publication Date: Apr 1, 1985 |
 Citations: 9 |
Reaction of HgCl 2 with [Rh 2(μ-Cl)(CO) 2(μ-CO)(μ-dppm) 2]Cl (dppm = bis(diphenylphosphino)methane) gives [Rh 2Cl 3(μ-HgCl)(CO) 2(μ-dppm) 2] in which only one Rh is oxidised by insertion into a HgCl bond, and which consequently contains an unusual asymmetric RhHgRh bridge.
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