Formation of β"-related composite precipitates in relation to enhanced thermal stability of Sc-alloyed Al-Mg-Si alloys

Abstract

The Al-Mg-Si alloys added with trace Sc demonstrates an improved thermal stability, as compared with that without Sc-addition. But the microstructural origin of the enhanced property is unclear. In the present study, the precipitates formed in an Al-Mg-Si-Sc alloy were studied in detail by atomic-resolution scanning transmission electron microscopy. It is shown that the dominant precipitates formed at the peak-aging condition are the disordered β" precipitates consisting of Sc-free β" sub-units and Sc-containing disordered regions, rather than the well-ordered β". Upon further aging, these disordered β" precipitates will evolve to β"/β'/B′/U2 composite precipitates. The formation of the composite precipitates is probably associated with the strong binding between Sc and Si atoms, and with the non-preference for Sc atoms to occupy the atomic sites of the β"-structure. Our study reveals the following: It is the formation of stabilized β"-related composite precipitates that enhances the thermal stability of the Sc-added Al-Mg-Si alloy.