Abstract
The thermolysis of germanium oxetanes and adducts of germanium- dioxolanes, oxazolidines and diazolidines with carbonyl compunds leads to transient dialkylgemanones R 2Ge=O characterized by addition of alkoxy- gemanes and oxagermacyclopentanes on the germanium—oxygen bond, and by insertion and ring expansion reactions with ethylene oxide, with formation of germadioxolanes.
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