Abstract

The enthalpies of combustion of α-, β-, γ- and δ-1,2,3,4,5,6-hexachlorocyclohexane (HCCH) isomers and of chlorocyclohexane (CCH), and the enthalpy of vaporization of CCH have been determined by precision combustion and vaporization calorimetry; the enthalpies of formation of these compounds are derived. These results are more reliable than values reported in the literature. The non-bonding interactions in these molecules are discussed using the group scheme, the electrostatic bond energy model and force field calculations.

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