Abstract
The secondary ozonide (SOZ) of limonene is a potential indoor pollutant from the gas-phase limonene/ozone-reaction. A screening in the liquid phase was performed to investigate the yield and stability of SOZs from ten cyclic monoterpenes. They were cryo-ozonolyzed in pentane, and the reaction mixtures were analyzed with GC–MS with negative and positive chemical ionization and electron ionization. The investigated terpenes were: limonene, 4-carene, 3-carene, 2-carene, terpinolene, (+)-α-pinene, (−)-β-pinene, isolimonene, sabinene and camphene. The only identified endo-SOZs were from: limonene, 3-carene, 4-carene and possibly isolimonene. Collision induced dissociation (CID) of the quasi-molecular-ions as a proxy measure of the stability of the pristine SOZs was investigated. LimoneneSOZ and 3-careneSOZ were found to be more stable than 4-careneSOZ and isolimoneneSOZ, which corresponded well to their relative yields. 3-careneSOZ was found to be a major product from the gas-phase ozonolysis.
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