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https://doi.org/10.1021/ol801055b
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Cite Journal: Organic Letters |  Publication Date: Jun 13, 2008 |
 Citations: 36 |
Affiliation: West Virginia University
A formal total synthesis of the oxopentaene macrolide antibiotic RK-397 has been achieved. Nine stereocenters were established by a combination of allylation and our asymmetric hydration reactions and a 1,5 anti-selective aldol reaction. The synthesis proceeded in 19 steps from simple achiral conjugated dienoates.
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