Abstract
This paper presents the development of artificial neural network models for the prediction of the daily maximum hourly mean of surface ozone concentration for the next day at rural and urban locations in central Poland. The models were generated with six input variables: forecasted basic meteorological parameters and the maximum O3 concentration recorded on the previous day and number of the month. The training data set covered the period from April 2015 to September 2015. An analogous data set of input variables, for the 2014 year, not used during the process of training the networks, was used as test data to examine the quality of these models. From the results of simulations for the year 2014, the average relative error values were equal to 15.3% and 15.7% for Belsk and Warsaw stations, respectively. The mean error (ME) value indicates a tendency to overestimate the predicted values by 4.8 µg/m3 for Belsk station and to underestimate the predicted values by 0.9 µg/m3 for Warsaw station. The analysis of days when the relative error value was >50% revealed that all predictions with extremely high relative error value were associated with relatively low daily maximum surface ozone concentration values that occurred suddenly due to a sharp drop in day-to-day ozone concentration values.
Highlights
IntroductionThe primary source of ground-level ozone is production through a chain of photochemical reactions involving NOx , CO and VOC
Ozone is a naturally occurring component of the atmosphere
The results indicate that differences between modeled and measured surface ozone concentration values are statistically significant
Summary
The primary source of ground-level ozone is production through a chain of photochemical reactions involving NOx , CO and VOC Organic Compounds) [1,2] Another natural source is the flux of ozone from the stratosphere to troposphere [3]. The concentration of surface ozone in a given area is determined by the combination of factors involved in its formation (photochemical reactions), destruction (dry deposition, chemical reactions) and transport (stratospheric intrusions, long-range transport). The relatively long life-time of the ozone molecule in the boundary layer (1–2 days) [7] enables it to be transported for long distances feeding the budget of areas located far from the source region. The lack of mechanisms that deplete ozone contribute to usually higher surface ozone concentrations at rural stations than at urban or suburban stations [8,9]
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