Abstract

The paper presents the investigations on producing spherical particles 65-110 μm in size using the energy of low temperature plasma (LTP). These particles are based on flow ash produced by the thermal power plant in Seversk, Tomsk region, Russia. The obtained spherical particles have no defects and are characterized by a smooth exterior surface. The test bench is designed to produce these particles. With due regard for plasma temperature field distribution, it is shown that the transition of fly ash particles to a state of viscous flow occurs at 20 mm distance from the plasma jet. The X-ray phase analysis is carried out for the both original state of fly ash powders and the particles obtained. This analysis shows that fly ash contains 56.23 wt.% SiO2; 20.61 wt.% Al2O3 and 17.55 wt.% Fe2O3 phases that mostly contribute to the integral (experimental) intensity of the diffraction maximum. The LTP treatment results in a complex redistribution of the amorphous phase amount in the obtained spherical particles, including the reduction of O2Si, phase, increase of O22Al20 and Fe2O3 phases and change in Al, O density of O22Al20 chemical unit cell.

Highlights

  • Cenospheres are produced by thermal power plants (TPP) as a byproduct of coal combustion

  • X-ray phase analysis After the low temperature plasma (LTP) treatment, fly ash and spherical particles produced thereof were subjected to the X-ray phase analysis (XRP)

  • The XRP analysis shows that such stable phases as SiO2, Al2O3, Fe2O3, TiO2, CaO, MgO are present in the original state of fly ash that is supported by its chemical composition

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Summary

Introduction

Cenospheres are produced by thermal power plants (TPP) as a byproduct of coal combustion. A cenosphere is a lightweight, inert, hollow sphere that ranges in size from 50 to 500 μm. The continuous and nonporous cenosphere walls have the thickness ranging from 2 to 10 μm. The content of spherical particles is represented mostly by nitrogen and carbon dioxide [1,2,3]. The unique combination of the low density, small size, spherical shape, high hardness, melting temperature, and chemical inertness of cenospheres stipulates for their wide use in construction and other industries. Cenospheres have a mixed vitreous transparent structure comprising 76% glass, 22% mineral substance, and 2% impurities and are represented by aluminosilicate glass, silica, mullite, calcite, iron oxides, calcium silicates, and sulfates

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