Fluoride removal using tartaric acid-modified rice husk biochar: Comprehensive batch and column studies

Abstract

Tartaric Acid-modified Rice Husk biochar (TARH) was evaluated as an efficient and cost-effective adsorbent to eliminate Fluoride (F¯) ions from aqueous solutions. F¯ is a major contaminant in groundwater, and current conventional treatment methods have certain drawbacks in treating higher concentrations of fluoride. The adsorption efficiency of TARH was improved by pre-treating rice husk biochar using tartaric acid (organic acid), which was confirmed by FT-IR measurement, indicating the presence of carboxylic acids, hydroxyl groups, and amine surface functional groups. The study optimized fluoride batch adsorption experiments by considering the parameters affecting adsorption, including pH, contact time, initial concentration, and adsorbent dosage using the Central Composite Design (CCD) from Response Surface Methodology (RSM). Maximum fluoride adsorption of 74.73% was attained by TARH under ideal circumstances (an initial fluoride concentration of 32 mg/L, a pH of 7, 0.25 g/100 mL of adsorbent dosage, and 180 minutes contact duration). The CCD models showed an exceptional R2 value of 0.988 for fluoride adsorption, illustrating their efficacy. Three-dimensional response surface plots were visualized to analyse the effects of control parameters on %adsorption, and statistical analysis supported the validity of the CCD model. Isotherm models and adsorption kinetics were investigated. The adsorption exhibited monolayer adsorption according to the Langmuir isotherm model and a pseudo-second-order rate-limiting phase due to chemisorption. The column adsorption studies were performed for various experimental factors such as influent fluoride concentration (4–16 ppm), influent flow rate (4–8 mL/min), and fixed-bed depth (4–8 cm). The experimental data were examined using the Yoon-Nelson, Thomas, and BDST models, which revealed a substantial correlation between the experimental findings and model predictions. The effectiveness of TARH was examined by regeneration study and case study was performed to evaluate the fluoride removal from actual water samples.