Fluorescent Carbon Nitride Nanoparticles for Picric Acid Sensing.

Abstract

Detection of nitroaromatic explosives is essential in the area of environmental safety. Fluorescent carbon nitride nanoparticles is a promising material for this purpose. Herein, we have prepared fluorescent carbon nitride nanoparticles (CNNPs) by one step thermal treatment of formamide. These fluorescent CNNPs is sensitive towards picric acid (PA) than other analytes both in aqueous medium and on test paper which is witnessed by fluorescence quenching based on inner filter effect (IFE). The PA detection with the fluorescent CNNPs is observed in the concentration ranges, 0 µM to 60 µM with linear range of 10 nM to 25 µM. The minimum detection limit in aqueous medium and solid phase are determined to be 26.20 nM and 10 µM respectively. Finally, the fluorescent CNNPs is applied for detection of PA in real water samples. The recoveries are in the ranges from 99.54 to 116.35% with relative standard deviation less than 3.85%. This proposed fluorescent method can act as suitable analytical technique to monitored PA concentration in water samples.