Fluorescence drainage profiles of thin liquid films

Abstract

Fluorescence drainage-profiles of thin liquid films formed from Rhodamine solutions containing anionic, cationic and non-ionic surfactants have been investigated. It is found that the influence of system variables such as electrolyte concentration, dye concentration, film environment and solution viscosity can be evaluated by means of the profiles. The addition of sodium chloride leads to the expansion (non-ionic surfactant), or contraction (anionic surfactant) of the profiles. In the case of the cationic surfactant, it reduces the number of fringes in the profiles. The height of selected fringes changes linearly with dye concentration, and no fringes are observed when the films are submerged in non-polar solvents. The influence of solution viscosity on film thickness and drainage rate is demonstrated by the number and frequency of fringes in the profile. The formation of first and second “black films” from solutions containing varying concentrations of sodium chloride can be shown.