Abstract
A rapid and sensitive on-line preconcentration method for spectrophotometric determination of chromium (VI) in nature water is described. Preconcentration and determination are based on (i) the quantitative and fast adsorption of chromium (VI) on the high surface area nanometer-size TiO2 (anatase) powders, which prepared by a sol-gel method from hydrolysis of TiCl4 and (ii) the quantitative and reproducible elution of Cr (VI) by 2.0 mol·L−1 HCl. A mini-column system for preconcentration is developed, Cr(VI) on the mini-column is eluted and merged with a stream water and DPCB (1,5-diphenylcarbazide) as the chromogenic reagent. The proposed system permits throughputs of 6 sample h−1 (0.001 μg·mL−1 Cr(VI)) or 20 sample h−1 (0.1 μg·mL−1 Cr(VI)). The preconcentration factor is 55. The detection limit is 0.8 ng · mL−1 Cr(VI). The reproducibility is satisfactory with a relative standard deviation of less than 3.35% (0.01 μg·mL−1 Cr(VI),n=5).
Published Version
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