Flow behavior of polymers during the roll-to-roll hot embossing process

Abstract

The roll-to-roll (R2R) hot embossing process is a recent advancement in the micro hot embossing process and is capable of continuously fabricating micro/nano-structures on polymers, with a high efficiency and a high throughput. However, the fast forming of the R2R hot embossing process limits the time for material flow and results in complicated flow behavior in the polymers. This study presents a fundamental investigation into the flow behavior of polymers and aims towards the comprehensive understanding of the R2R hot embossing process. A three-dimensional (3D) finite element (FE) model based on the viscoelastic model of polymers is established and validated for the fabrication of micro-pyramids using the R2R hot embossing process. The deformation and recovery of micro-pyramids on poly(vinyl chloride) (PVC) film are analyzed in the filling stage and the demolding stage, respectively. Firstly, in the analysis of the filling stage, the temperature distribution on the PVC film is discussed. A large temperature gradient is observed along the thickness direction of the PVC film and the temperature of the top surface is found to be higher than that of the bottom surface, due to the poor thermal conductivity of PVC. In addition, creep strains are demonstrated to depend highly on the temperature and are also observed to concentrate on the top layer of the PVC film because of high local temperature. In the demolding stage, the recovery of the embossed micro-pyramids is obvious. The cooling process is shown to be efficient for the reduction of recovery, especially when the mold temperature is high. In conclusion, this research advances the understanding of the flow behavior of polymers in the R2R hot embossing process and might help in the development of the highly accurate and highly efficient fabrication of microstructures on polymers.