Abstract

The sedimentation kinetics of an ochre suspension in salt (NaCl)-containing aqueous media was studied in the presence of ionogenic (anionic, A, and cationic, C) acrylamide copolymers with high molecular weight (M > 2 × 106) using a VT–0.5 torsion balance. The ionic strength of the dispersion medium varied in the wide range from 0.001 N to 0.4 N. The flocculation proceeded predominantly by a `bridge' mechanism, and the fraction of macromolecules inactive in the acts of floccule formation was significantly higher for C copolymer as compared with A copolymer. A drastic fall in the flocculating activities of A and C copolymers when passing from salt-free to salt-containing media is caused mainly by two following events:

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