Flexible fabrication of a novel SiO2/AF/ZIF-L composite embedded with MOF structure and its thermal insulation properties

Abstract

ZIF-L, a metal-organic framework (MOF) material, has a two-dimensional (2D) foliation, a large specific surface area, excellent thermal stability and CO2 adsorption performance, respectively. In this work, in order to further improve the thermal insulation performance of SiO2 aerogel composite fabrics, ZIF-L powder was first prepared as a reinforcing particle, and then added to silica aerogel. Finally, SiO2/AF/ZIF-L composites were obtained by solution impregnation method. The influence of different ZIF-L concentrations on the insulation performance of composites and their influencing factors were studied. Furthermore, these composites were fully characterized using BET measurement, Instron 5967, precision transient thermal performance tester, infrared thermal imager, insulation performance test, thermogravimetric analyzer, and dynamic thermomechanical analyzer. The results showed that 0.12% SiO2/AF/ZIF-L composites had excellent thermal insulation performance, with a thermal conductivity as low as 0.029 W/(m·K). In addition, SiO2/AF/ZIF-L composites fabricated by atmospheric drying method had the best thermal insulation performance under the conditions of gel time of 24 h, hydrolysis time of 5 h, and polycondensation pH value of 5–6.