Abstract

A commercial PWR fuel sample with a local burn-up of about 240MWd/kgHM was annealed in a Knudsen cell mass spectrometer system with a heating rate of 10K/min up to 2750K at which temperature the sample was completely vaporized. The release of fission gases and fission products was studied as a function of temperature. In one of the runs the heating was interrupted successively at 900, 1500 and 1860K and at each step a small fragment of the sample was examined by SEM and analysed by energy dispersive electron probe microanalysis. The release behaviour of volatile, gaseous and other less volatile fission products is presented and analysed with the EFFUS program and related to the structural changes of the fuel.

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