First stereoselective total synthesis of pectinolide C and total synthesis of pectinolide A

Gowravaram Sabitha,Sukant Kishore Das,Praveen Ankireddy,J.S Yadav

doi:10.1016/j.tetlet.2012.12.039

First stereoselective total synthesis of pectinolide C and total synthesis of pectinolide A

Gowravaram Sabitha, Sukant Kishore Das + Show 2 more

https://doi.org/10.1016/j.tetlet.2012.12.039

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Journal: Tetrahedron Letters	Publication Date: Dec 20, 2012
Citations: 10

Affiliation: Indian Institute of Chemical Technology

#Stereoselective Synthesis #Stereoselective Total Synthesis + Show 3 more

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Abstract

The first stereoselective synthesis of pectinolide C and synthesis of pectinolide A, from easily accessible 1-hexyne and d-mannitol are reported in a convergent manner. The salient features include acetylenic addition to the chiral aldehyde and Still–Gennari olefination.

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