First intramolecular alkyne–CO insertion reactions in aminocarbene complexes of chromium: formation of condensed heterocycles following extensive hydrogen migrations

M Audouin,S Blandinières,H Rudler,A Parlier

doi:10.1039/c39900000023

First intramolecular alkyne–CO insertion reactions in aminocarbene complexes of chromium: formation of condensed heterocycles following extensive hydrogen migrations

M Audouin, S Blandinières + Show 2 more

https://doi.org/10.1039/c39900000023

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Journal: J. Chem. Soc., Chem. Commun.	Publication Date: Jan 1, 1990
Citations: 8

#Aminocarbene Complexes Of Chromium #Complexes Insertion + Show 8 more

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Abstract

The aminocarbene complexes (CO)5CrC(Me)[N(Me)(CH2)3CCPh](6) and (CO)5CrC[graphic omitted][(CH2)3CCMe](14) lead, upon heating in benzene, to the polycyclic triple bond and CO inserted products C15H15NO (12) and C12H15NO (19) through multiple C–H activations.

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