Abstract

Chemical analysis of archaeological objects is an important part of current investigations. In the presented study, a soil from an archaeological vessel from rescue excavation close to the village Držovice (Central Moravia Region, Czech Republic; findings dated to Eneolithic period) was analyzed using gas chromatography/mass spectrometry and firstly in archaeological science by atmospheric pressure solids analysis probe with atmospheric pressure chemical ionization mass spectrometry. Miliacin, a chemical marker of a broomcorn millet, was unambiguously confirmed by both techniques. The obtained results can help to understand the diet habits of Corded Ware population and connection between Central Europe and Asia, where broomcorn millet has been domesticated. The identification of miliacin as a “chemical imprint” of millet from the end of Eneolithic period of Moravia is therefore extraordinarily important.

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