Abstract
An algorithm for calculating the leading relativistic corrections for $D$ states of atoms with an arbitrary number of electrons with all-electron explicitly correlated Gaussian functions is derived and tested in calculations for the helium and beryllium atoms. The finite-nuclear-mass approach used enables us to determine the isotopic shifts of the corrections. The results for interstate transitions for $^{1}D$ states of the helium atom are compared with previous calculations. The results for the beryllium atom are compared with the experimental values, as these are high-accuracy calculations of $D$ states of a four-electron atom performed with the inclusion of the leading relativistic corrections. The calculated and experimental values agree with each other within the experimental error bar.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
