Abstract

The frequency dependence of the longitudinal relaxation time T 1( v) of different liquids confined to microporous glass features a distinct difference between polar and nonpolar adsorbates. This finding is explained by “weak” and “strong” adsorption, respectively. The T 1 dispersion of polar adsorbates can be described with the aid of Lévy walk statistics of “bulk-mediated surface diffusion” recently suggested by Bychuk and O'Shaughnessy

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