Ficus retusa-stabilized gold and silver nanoparticles: Controlled synthesis, spectroscopic characterization, and sensing properties.

Abstract

Ficus retusa was used as reducing and stabilizing agent in the green synthesis of silver and gold nanoparticles with high dispersion stability and controllable size and shape. The controlling of reaction conditions i.e. contact time, extract quantity, metal concentration, and pH value enables the tuning of the particle size and size distribution of the metal nanoparticles. UV-visible spectroscopy was used to follow the spectral profile changes of the surface plasmon resonance of the metal nanoparticles due to different treatments. The surface plasmon resonance varies between 400 and 432 nm and between 522 and 554 nm for silver and gold nanoparticles, respectively, depending on the different reaction parameters. Atomic force and transmission electron microscopy results confirmed the success of preparation of spherical silver (15 nm) and gold (10-25 nm) nanoparticles with narrow size-distribution. Fourier transform infrared spectroscopy suggested the phenolic compounds play the key role in the reduction and stabilizing of metal ions. The colorimetric sensitivity of silver and gold nanoparticles to detect the presence of heavy metals in water was studied.