Fickian Non-Gaussian Diffusion in Glass-Forming Liquids.

Abstract

Fickian yet non-Gaussian diffusion (FnGD), a most intriguing open issue in soft matter, is generically associated with some dynamical and/or structural heterogeneity of the environment. Here we investigate the features of FnGD in glass-forming liquids, the epitome of dynamical heterogeneity, drawing on experiments on hard-sphere colloidal suspensions and simulations of a simple model of molecular liquid. We demonstrate that FnGD strengthens on approaching the glass transition, by identifying distinct timescales for Fickianity, τ_{F}, and for restoring of Gaussianity, τ_{G}>τ_{F}, as well as their associated length scales, ξ_{F} and ξ_{G}. We find τ_{G}∝τ_{F}^{γ} with γ≃1.8 for both systems. In the deep FnGD regime, the displacement distributions display exponential tails. We show that, in simulations, the time-dependent decay lengths l(t) at different temperatures all collapse onto a power-law master curve [l(t)/(ξ_{G})]∝(t/τ_{G})^{α}, with α=0.33. A similar collapse, if less sharp, is also found in experiments, seemingly with the same exponent α. We further discuss the connections of the timescales and length scales characterizing FnGD with structural relaxation and dynamic heterogeneity.