Abstract

The temperature dependence of dielectric properties and photoluminescence (PL) of glass semiconductor SbSI is studied. According to measurements of the dielectric constant and polarization the first-order structural phase transition into the polar state (dipolar glass) is realized at T = 198 K. A complex spectrum of the found PL in the glass SbSI is related to two types of structural units. A wide radiation band, PL maximum location and large Stocks shift prove the existence of a strong electron-phonon interaction.

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