Abstract
Fe-based catalysts have been prepared by pyrolyzing ClFeTMPP (Cl–Fe tetramethoxyphenyl porphyrin) or Fe acetate adsorbed on PTCDA (perylene tetracarboxylic dianhydride) or on prepyrolyzed PTCDA (p-PTCDA). The catalysts which were already well characterized in terms of active FeN 4/C and FeN 2/C catalytic sites (J. Phys. Chem. B 106 (2002) 8705) are now characterized by RRDE experiments to determine the values of the apparent number of electron transferred ( n) and the percentage of peroxide (%H 2O 2) released during the oxygen reduction reaction (ORR) in H 2SO 4 at pH 1. A direct correlation is found between the relative abundance of the FeN 2/C catalytic site in these materials, their catalytic activity and the value of n. The correlation is inverse for %H 2O 2. The best catalysts at their maximum catalytic activity are characterized by n>3.9 and %H 2O 2<5%, equivalent to a value of %H 2O 2 released by a 2 wt.% Pt/C catalyst. It is shown that even low peroxide levels of the order of 5 vol% in H 2SO 4 are able to decompose the catalytic sites releasing iron ions in the H 2SO 4 solution. The loss of catalytic activity correlates directly with the loss of iron ions by these catalysts. All the catalysts have been tested at the cathode of single membrane electrode assemblies (MEAs). The slow decrease in performance in fuel cell stability tests is interpreted as the result of the detrimental effect that has H 2O 2, released during ORR, on the chemical integrity of the nonnoble metal catalytic sites at work at the fuel cell cathodes.
Published Version
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