Abstract

Organometallic halide perovskite solar cells such as MAPbI3 have shown great promise as a low-cost, high-efficiency photovoltaic candidate. Recent studies demonstrated that by substituting an appropriate amount I ions of MAPbI3 with Br ions, the device performance parameters, such as moisture stability or power conversion efficiency, can be further optimized. In this study, using time-resolved optical reflectivity to track the carrier dynamics in MAPb(I1- xBr x)3 films with different Br contents, we found that photocarriers in MAPb(I1- xBr x)3 films with x = 0.01 and 0.02 diffuse much faster than those in films with other Br contents. We suggest that the faster charge carrier diffusion benefits from larger crystal grain size. As a result, this suppresses electron and hole recombination and increases the carrier extraction efficiency, in agreement with the higher power conversion efficiency reported previously.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.