Facile synthesis of N-vinylimidazole-based hydrogels via frontal polymerization and investigation of their performance on adsorption of copper ions

Abstract

We report a new facile strategy for quickly synthesizing pH sensitive poly(VI-co-HEA) hydrogels (VI = N-vinylimidazole; HEA = 2-hydroxyethyl acrylate) by frontal polymerization. The appropriate amounts of VI, HEA, and ammonium persulfate (APS)/N,N,N′,N′-tetramethylethylenediamine (TMEDA) couple redox initiator were mixed together at ambient temperature in the presence of glycerol as the solvent medium. Frontal polymerization (FP) was initiated by heating the upper side of the mixture with a soldering iron. Once initiated, no further energy was required for the polymerization to occur. The dependence of the front velocity and front temperature on the VI/HEA weight ratios were investigated. The pH sensitive behavior, morphology, and heavy metal removal study of poly(VI-co-HEA) hydrogels prepared via FP were comparatively investigated on the basis of swelling measurements, scanning electron microscopy, and inductively coupling plasma spectrometer. Results show that the poly(VI-co-HEA) hydrogels prepared via FP exhibit good pH sensitivity and adsorption capacity. The FP can be exploited as an alternative means for synthesis of pH sensitive hydrogels in a fast and efficient way. The as-prepared hydrogels can be applied to remove heavy metals. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 4005–4012, 2010