Facile Synthesis of Mn-Doped ZnS Nanocrystals and Determination of Critical Temperature for Lattice Diffusion Process

Abstract

High-quality Mn:ZnS doped nanocrystals (d-dots) with photoluminescence (PL) quantum yield (QY) of 50-70% have been synthesized based on nucleation-doping strategy by choosing 1-dodecanethiol (DDT) as the capping ligand. Controlling the growth of small-sized MnS core nanoclusters was successfully achieved by changing the injection temperature of sulfur precursor, the growth time of MnS nuclei, and the amount of DDT. Furthermore, MnS/ZnS core/shell d-dots with a diffusion layer at the interface between the MnS core and the ZnS shell were fabricated through an overcoating of the ZnS shell layer on the presynthesized MnS core nanoclusters. The resulting monodisperse d-dots exhibited spherical shape with a zinc-blende crystal structure. The critical temperature for lattice diffusion of Mn ions in the ZnS host lattice was determined to be about 260 degrees C by annealing the presynthesized and purified Mn:ZnS d-dots.