Abstract
Abstract Sulfoxides were found to be deoxygenated slowly with thiosilane (PhSSiMe3), while deoxygenation of sulfoxides with the thiosilane proceeded smoothly in the presence of a catalytic amount of tetra-butylammonium bromide. For a preparative purpose, a mixed system of thiol and trimethylsilyl chloride can be used successfully for both deoxygenation of sulfoxides and deimination of sulfimides.
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