Abstract
Recently, bimetallic nanocomposites have been prepared and used in the fields of sensing, catalysis, energy and medicine. However, there are few reports on the preparation and application of new antimony-metal nanocomposites based on two-dimensional antimonene (AM). Herein, Sb2O3-CuO nanocomposites were facilely synthesized by using microwave-assisted heating the mixture solution of AM and Cu2+ ions and utilized for catalytic degradation of p-nitrophenol (PNP). Interestingly, in the mixed solution of AM and various metal ions (Cu2+, Co2+, Mn2+), only the mixture of AM and Cu2+ ions showed efficient fading and absorption reduction effects on PNP after being heated. A series of characterization on morphology and elemental composition confirmed that the nanocomposites obtained after microwave heating was composed of Sb, Cu, O elements (namely Sb2O3-CuO), and was a layered structure loaded with numerous irregular particles. Compared with other catalysts, the nanocomposite has higher catalytic efficiency (the rate constant of 1.07 s−1), and was capable of degrading 96 % of PNP with only 3 s reaction. Electron spin resonance spectroscopy and liquid chromatography-mass spectrometry analysis demonstrated that the copper-mediated Fenton-like reaction in the nanocomposites induced hydroxyl radicals which can efficiently attack and degrade PNP. This study presents a novel approach to the synthesis of antimony-metal nanocomposites and provides a potential solution for the treatment of organic pollutants.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call