Abstract
We demonstrate for the first time the in-situ synthesis of Pd nanocubes (PdNC) on nitrogen-doped reduced graphene oxide (NRGO) for facile organic transformations wherein the cubic morphology of Pd can only be realized by precision-controlled acid additions in the tune of 0.02 pH variations in the reaction medium. Due to the intimate contact arising from atom-by-atom addition of Pd on NRGO, the composite has exhibited a pronounced catalyst to support charge transfer effect, shift in the d-band center, and lowering of charge-transfer resistance when compared with PdNC-NRGO ex-situ composites prepared by mixing of the preformed components of PdNC and NRGO or PdNCs alone. The activities of these catalysts were tested for the Suzuki coupling and nitroarene reduction reactions using water as an industry-friendly solvent. In both, the in-situ deposited sample exhibited substantially higher catalytic activity as well as stability when compared with an ex-situ sample or pure PdNCs. We show that a very high turnover frequency of ~31300 h−1 and ~900 h−1 are achievable by using the in-situ deposited PdNC-NRGO composite for Suzuki coupling reactions and nitroarene reduction respectively, better than the state-of-the-art catalysts developed recently, in addition to high recyclability.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.