Abstract
The interaction of square-planar metal complexes through space is of fundamental interest and relevant for the potential cooperative catalysis of two metal complex sites. In order to elucidate gold/gold, gold/porphyrin, and porphyrin/porphyrin interactions in the formal oxidation states +III and +II (after reduction) and in the excited triplet state after light excitation, a Pacman bis(gold(III)) complex [Au2(DPD)][PF6]2 with square-planar face-to-face gold(porphyrin) moieties has been prepared and characterized. Absorption and luminescence spectroscopy, cyclic voltammetry, and EPR spectroscopy on [Au2(DPD)]n+ and a mononuclear reference are complemented by DFT and TDDFT calculations.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
