Fabrication and thermal shock behavior of ZrO2 toughened magnesia aggregates

Abstract

MgO-based refractories have been regarded as ideal linings for various furnaces owing to high refractoriness and excellent corrosion resistance to basic slag. However, thermal shock damage resulting from poor thermal shock resistance (TSR) of magnesia is the common failing. The present work aimed at improving TSR of magnesia aggregates by introducing microscale monoclinic ZrO2. The results showed that the ZrO2 added could increase cation vacancy concentration and inhibit abnormal growth of MgO grains, which therefore enhanced densification of the specimens. However, when the ZrO2 amount exceeded 15 wt%, densification decreased slightly due to agglomeration of ZrO2 and formation of more microcracks at the MgO grain boundaries. With increasing ZrO2 content, although the flexural strength degraded, the fracture toughness increased constantly because of the toughening effects of crack deflection and crack branching. Besides, although the addition of ZrO2 decreased the thermal conductivity, TSR of the specimens was significantly improved with increasing ZrO2 content due to the increase in toughness and decrease in strength, thermal expansion coefficient as well as Young's modulus. After thermal shock tests, 15 wt% ZrO2 containing specimen exhibited the highest TSR, whose residual strength ratio was about triple of that of the pure magnesia specimen. However, further increasing ZrO2 content to 20 wt% reduced the TSR attributing to the spalling of intergranular ZrO2 agglomerations.