Fabrication and characterization of mesoporous yolk-shell nanocomposites as an effective reusable heterogeneous base catalyst for the synthesis of ortho-aminocarbonitrile tetrahydronaphthalenes.

Abstract

Mesoporous yolk-shell nanocomposites (MYSNs) were loaded with a mobile CaMg core inside the silica shell. CaMg@MYS nanocomposites have been effectively prepared inside the inner cavity of a novel structure that consists of hollow mesoporous silica spheres. Tetraethyl orthosilicate (TEOS) and an amount of cetyltrimethylammonium bromide (CTAB) are coated on the carbon spheres used as a hard template in the multi-step synthetic procedure. In this method, the target products were obtained in high to excellent yields between 87-96% and quick response times between 10-20 minutes under mild conditions. The CaMg@MYS catalyst shows promise as an efficient and reusable catalyst in multicomponent processes. The CaMg@MYS multi-yolk spheres compared to metal oxide nanostructures indicated both high catalytic performance and a significant factor as a novelty. To identify each product, FT-IR, 1H NMR, and melting point techniques were applied. Also, in order to characterize the prepared catalysts, FT-IR, XRD, FE-SEM, EDS, elemental mapping, and HR-TEM techniques were applied.