Exploring cyclic olefin copolymer (COC) for flexible silver nanowire electrode

Abstract

The development of flexible electronic devices has been a primary focus in various fields, and silver nanowire (Ag NW) networks show significant promise due to their unique electrical and mechanical properties. However, achieving well-defined and stable nanowire coatings on polymer substrates remains challenging. This work presents a novel and simple approach for directly coating Ag NWs on cyclic olefin copolymer (COC) substrates utilizing ultraviolet/ozone (UVO) treatment, a method not previously demonstrated for this specific material system up to our knowledge. The compatibility of this approach with COC eliminates the need for complex pre- and post-treatment processes, making it a more straightforward and environmentally friendly way to improve adhesion between Ag NWs and COC. The Ag NWs/COC electrodes exhibited excellent optoelectrical performance, with a high optical transmittance of 84% and a low sheet resistance of 13 Ω/sq—metrics that compare favorably to industry standards for transparent conductive films. Additionally, the Ag NWs/COC electrodes displayed excellent mechanical stability, showing no changes in sheet resistance after both tape adhesion and film bending tests. The novelty of the presented Ag NW-COC system, combined with the simplicity and environmental benefits of the UVO coating approach, as well as the demonstrated performance and stability of the resulting electrodes, make this work a significant advancement towards realizing the commercial potential of flexible electronics for biocompatible and wearable device applications.