Abstract
Lithium-collaborating organic batteries (Li-[28]hexs) were investigated with [28]hexaphyrin(1.1.1.1.1.1) as an active electrode material. Each hexaphyrin of [28]Hex cathode ideally involved four electrons per unit cycle and performed a typical charge/discharge processes of Li-organic battery. Li-[28]Hex batteries set with fast charging rates showed reasonably stable charge and discharge performances over 200 cycles even though it caused incomplete (2~3 electrons) charge/discharge cycles due to failing the complete charging process. UV absorption changes of [28]hexaphyrin in CH2Cl2 were supplementary for the electrochemical oxidation, which performed a conversion from [28]hexaphyrin to [26]hexaphyrin.
Highlights
There is no doubt that the sources of our energy consumptions are essential and dictate the quality of our lives, the investigation of electrical power suppliers such as portable batteries have been crucial
Molecules that are fully reversible with multiple oxidation states are great candidates for building an efficient battery system
Preparation of Li-[28]Hexaphyrin Batteries and Investigation of the Battery Behaviors meso-Aryl hexaphyins have been isolated in two oxidation states, exhibiting two distinct meso-Aryl hexaphyins have been isolated in two oxidation states, exhibiting two distinct conjugate systems, 26 and 28 π-electrons, whose conjugation was converted to the other by chemical conjugate systems, 26 and 28 π-electrons, whose conjugation was converted to the other by chemical redox-reactions (Figure 1) [24,30]
Summary
There is no doubt that the sources of our energy consumptions are essential and dictate the quality of our lives, the investigation of electrical power suppliers such as portable batteries have been crucial. Portable battery systems have been convenient energy suppliers and various types of batteries have been proposed and developed substantially [1,2,3,4,5,6]. Li-organic batteries have been extensively investigated by adopting various suitable organic molecules [7,8]. We have to comprehend the chemistries occurring in the electronic systems. Molecules that are fully reversible with multiple oxidation states are great candidates for building an efficient battery system. Norcorrole molecule stabilizes its antiaromaticity successfully by tetradentate–metal ligation with
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