Abstract

Underground engineering, especially deep geotechnical engineering, is often affected alternately by groundwater infiltration and ventilation drying during construction and use. In addition, acid rain, mineral dissolution, acid deposition, and other factors make groundwater acidic. This caused the underground structure to erode and has also threatened its safety and durability. In this study, both the physical and mechanical properties under acid dry-wet (A-D-W) cycles were investigated. Deep sandstone was treated repeatedly under acid cycling, and its physical parameters were measured. Uniaxial compressive strength tests and microtests were carried out. Finally, using a combination of scanning electron microscopy (SEM) and backscatter electron images (BSE), the microstructural changes of sandstone under the combined action of an acidic environment and a dry-wet cycle were described. The test results show that the mass, P-wave velocity, peak stress, and elastic modulus of sandstone after the A-D-W cycles decreased by 0.43%, 7.87%, 70.20%, and 88.10%, respectively. With the increase in the number of cycles, the loss of these indicators increased. However, the peak strain increased with an average increase of 55.8%. In addition, 10 cycles are the critical point for physical and mechanical indicators of the A-D-W cycles. After 10 cycles, the changes of various indicators increase rapidly. Microscopic analysis shows that the reasons of this phenomenon were that the specimen was corroded by the sulfuric acid solution, which resulted in the development of pores and cracks and the decline of physical and mechanical properties. Conversely, the development of pores was hindered by sediment, which slowed down the decline rate of the physical and mechanical indexes of specimens, but this phenomenon disappeared with the increase of A-D-W cycles. Based on the analysis of the experimental phenomena, the constitutive model of uniaxial compression based on Weibull damage variable has been established in this article, and the model has the best effect in acid solution with less cycle times or pH value of solution greater than 6.

Highlights

  • Water-rock interaction is an important driving force for the evolution of the near-surface environment

  • Sufficient research works have been done on the variation of static rock mechanical parameters under dry-wet cycling [5,6,7,8]. e results show that the drywet cycling has an obvious deterioration effect on the basic mechanical properties of rock, such as compressive strength, elastic modulus, cohesion, and the internal friction angle

  • The study of the variation of mechanical parameters of rock materials under a dynamic environment is becoming more and more abundant, Zhou et al [9] found that the dynamic compressive strength and elastic modulus of sandstone decreased with the increase of the number of dry-wet cycles, and the empirical equation of the effect of the strain rate and dry-wet cycles on the dynamic compressive strength of the rock materials was established through experiments

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Summary

Introduction

Water-rock interaction is an important driving force for the evolution of the near-surface environment. Ey found that the basic reason for the decline of the mechanical properties of rocks was that the pH value of the chemical solution changed the porosity and microdamage evolution of the rocks [23] They analyzed the deterioration rule of sandstone mechanical parameters under acid-base conditions [24, 25] and developed a numerical simulation program based on an improved Duncan–Chang constitutive model [26]. After soaking in a sulfuric acid solution with pH values of 4 to 7 for five days, the sandstone is dried and wetted 0, 5, 10, and 15 times, respectively, and uniaxial compressive strength tests and microtests are carried out to study the change rules of the physical, mechanical, and the evolution process of the microstructure. The uniaxial damage model of the sandstones were established, and its applicability and accuracy were evaluated

Materials and Methods
Test Method
C O Mg Al Si S Ca Fe
Results and Discussion
Establishment of Uniaxial Damage Model
Conclusions
Full Text
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