Experimental study of the effect of material and arrangement of electrodes and voltage on the electro-remediation of saturated clays containing chloride and sulfate ions

Abstract

Electro-remediation process (ERP) is used for dewatering and decontaminating of the soil and improving its mechanical properties. In this study, the effect of voltage, electrode materials, and their arrangement on ERP were studied. The saturated clayey soil was remolded in four boxes at a dry density of 16.2 kN/m3. The process was performed in three stages. The chemical tests at the end of ERP indicated that the absorption of chloride ions in the anode may differ from 89 to 642% due to electro-migration phenomenon. The pH of the soil decreases in anode zone and increases towards the cathode zone. Up to 92% of the sulfate ions were transported and accumulated in the anode. However, in highly contaminated soil, the absorption ratio is 5% in the cathode due to the domination of electro-osmosis process. It was indicated that the electro-osmosis permeability coefficient (Ke) depends on the applied voltage, the soil type, and temperature and its reduction versus time is inversely related to applied voltage. Also, sulfate ions reduced by 74% in the anode due to a change in absorption direction. The results showed that the optimum configuration is linear along with a voltage of 18 V.