Abstract
Phase compositions of B-Fe-Mn-V alloys were studied by several experimental methods (DTA measurement, X-ray diffractions, and scanning electron microscopy). Besides the experimental study of the quaternary system, thermodynamic modelling of the ternary B-Mn-V system by the Calphad method and thermodynamic calculations for the quaternary B-Fe-Mn-V system were performed. Calculations for the quaternary system are based on the ternary subsystems (B-Mn-V, B-Fe-V, B-Fe-Mn, and Fe-Mn-V). Boron is modelled as an interstitial element in all solid solutions of vanadium, manganese, and iron. Very good agreement between experimental results and thermodynamic calculations was achieved. The created thermodynamic database is suitable for thermodynamic calculations of phase diagrams for all the ternary subsystems and also for the B-Fe-Mn-V quaternary system.
Highlights
Very good agreement between experimental results and thermodynamic calculations was achieved. e created thermodynamic database is suitable for thermodynamic calculations of phase diagrams for all the ternary subsystems and for the B-Fe-Mn-V quaternary system
E present work is focused on an experimental study of phase composition of the B-Fe-Mn-V alloys and thermodynamic calculations of phase equilibria in the B-Fe-Mn-V quaternary system. e thermodynamic calculations are based on ternary subsystems. erefore, thermodynamic modelling of the ternary B-Mn-V system by the Calphad method was done in the scope of this work
Besides the study of the B-Fe-Mn-V phase diagram, the aim of this work is the verification of the database based on ternary systems (B-Mn-V, B-Fe-V, B-Fe-Mn, and Fe-Mn-V) for calculations of the quaternary system
Summary
E present work is focused on an experimental study of phase composition of the B-Fe-Mn-V alloys and thermodynamic calculations of phase equilibria in the B-Fe-Mn-V quaternary system. e thermodynamic calculations are based on ternary subsystems. erefore, thermodynamic modelling of the ternary B-Mn-V system by the Calphad method was done in the scope of this work. E present work is focused on an experimental study of phase composition of the B-Fe-Mn-V alloys and thermodynamic calculations of phase equilibria in the B-Fe-Mn-V quaternary system. E thermodynamic calculations are based on ternary subsystems. Erefore, thermodynamic modelling of the ternary B-Mn-V system by the Calphad method was done in the scope of this work. Besides the study of the B-Fe-Mn-V phase diagram, the aim of this work is the verification of the database based on ternary systems (B-Mn-V, B-Fe-V, B-Fe-Mn, and Fe-Mn-V) for calculations of the quaternary system
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