Abstract
AbstractFurfural is a very promising product of lignocellulosic biomass‐based biorefineries and has the potential to become a useful resource for further conversion and utilization. Aquatic plants show an enormous potential as feedstock since they do not compete for land use, and they require minimal water consumption in a biorefinery concept due to their very high water content. This work is focused on experimental studies of furfural production from water hyacinth (Eichhornia crassipes) by means of aqueous, acid‐catalyzed dehydration. The temperature range of the process, and the acid and seawater presence were chosen based on the previous relevant studies. The aim of the study was to determine whether water hyacinth is suitable for furfural production. The experiments were performed between 160°C and 200°C with a water hyacinth concentration of 2 wt%. The results suggest that the effects of acid catalyst presence on biomass dehydration are similar to the case of pure pentose dehydration. Furthermore, the addition of seawater did not have a positive catalytic effect in terms of the furfural yield. The maximum yield was 53.2 mol% based on the C5 sugar content in the original biomass. The furfural yield of 7.9 wt% of water hyacinth input was comparable to the yield of feedstocks such as corn cob, bagasse, and oat's residue and higher than the cases of rice straw or hulls. Thanks to the comparatively high pentose potential, water hyacinth shows promising results as a candidate feedstock for furfural production. A certain variability of pentosan should be taken into account, as the chemical composition of the plant depends on the source and harvesting seasons.
Highlights
Greenhouse gas emission restrictions and the increasing energy prices are among the main reasons for an increasing need for renewable alternatives for fossil fuel‐based products
This paper presents an experimental study on furfural production from water hyacinth by the means of aqueous acid‐catalyzed dehydration, aiming to the determination of this feedstock's potential regarding this particular application
The furfural yield was examined for different sets of process conditions, in order to study the effect of the reaction temperature and the utilization of different acids and seawater as secondary catalyst on the overall process efficiency
Summary
Greenhouse gas emission restrictions and the increasing energy prices are among the main reasons for an increasing need for renewable alternatives for fossil fuel‐based products. A biorefinery is an conversion system concept that can produce multiple energy carriers, chemicals, materials, and food and feed products from biomass feedstocks. Furfural is a platform chemical with the potential to replace fossil oil‐derived products as an intermediate in the chemical industry and to be the starting material for biofuel blends. Furfural promises to be a very important product of Energy Sci Eng. 2019;7:2155–2164. . | 2156 the lignocellulosic biomass‐based biorefinery concept while having the potential to become a useful source of further utilization.[1] the current furfural market is not large enough for this product to be perceived as a platform chemical. More research is needed, mainly on the development of appropriate chemical processes concerning the production of this green platform chemical and the derived biofuel(s)
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