Experimental Investigations on a Novel Chemical Looping Combustion Configuration

Abstract

Chemical Looping Combustion (CLC) is a promising novel combustion technology involving inherent separation of carbon dioxide with minimum energy penalty. An oxygen carrier is employed to continuously transfer oxygen from the air reactor to the fuel reactor where the oxygen is delivered to the fuel. Consequently, direct contact between the air and fuel is prevented. The resulting flue gas is CO<sub>2<sub/>-rich, without N<sub>2<sub/> dilution. The reduced oxygen carrier is then transported back to the air reactor for re-oxidation purposes, hence forming a chemical loop.Various CLC configurations have already been developed and tested on laboratory scales. However, more investigations are required to achieve feasible CLC processes. Among the different points to address, control of the solid circulation rate between the two reactors is of the highest importance regarding its effect on achievement of an appropriate oxygen transfer rate and solid oxidation degrees. Moreover, minimization of gas leakage between the fuel and air reactors is another important issue to be considered. A novel CLC configuration is proposed where reactions are carried out in two interconnected bubbling fluidized beds. Solid circulation rate control is achieved independently of gas flow rate in the reactors through use of pneumatic non-mechanical valves (L-valves). Moreover, loopseals are employed to minimize gas leakage while transferring solids.Experimental results from operation of a 10 kW<sub>th<sub/> equivalent cold prototype are presented in this paper. The effect of operating variables on the solid circulation rate, gas leakage between the two beds and the pressure balance on all of the process elements is studied. The results demonstrate stable solid circulation with efficient control of the solid flow rate and effective gas tightness of the system.