Experimental investigation of soot formation in inverse diffusion flames of CO2 and N2 addition: Isolation of dilution and thermal effects

Abstract

ABSTRACT This experimental study compares the flame structure, temperature, and soot formation characteristics of normal (NDFs) and inverse diffusion flames (IDFs), evaluates the effect of CO2 addition, and isolates the thermal and dilution effects of CO2 and N2 addition on soot formation in IDFs. A hyperspectral imager using the TR-GSVD algorithm measures IDFs with different CO2 addition (XD) in the oxidant, with N2 addition as the comparison. In contrast to NDFs, IDFs have an opened tip, and the visible flame height and flame width decrease as XD grows. IDFs have a higher peak temperature than NDFs, but their peak soot volume fraction is substantially lower. Compared with N2 addition at the same XD, CO2 addition narrows IDFs and makes the reaction zone visible, and the peak temperature of CO2 addition is 350 K lower than that of N2 addition. The suppression effect of CO2 on soot formation is more potent than N2, with a soot formation rate of 30% that of N2 addition and a soot loading of 20–60%. The activation energy of soot formation reaction with CO2 addition is higher than N2 addition. The isolating results reveal that the thermal effect contributes to the main suppression effect of CO2 addition on soot formation, while the dilution effect of N2 addition is stronger than its thermal effect.