Abstract

Manufactured nanoparticles (NPs), including titanium dioxide nanoparticles (nTiO2), now enter in the formulation of several commercial products. Some studies have been carried out to assess the resistance of protective gloves against NPs, they have generally not considered the conditions prevailing in occupational settings.This study was designed to evaluate the behavior of protective gloves materials against NPs in solution under conditions simulating occupational use. Mechanical deformations, simulating those produced by flexing the hand, were applied to nitrile rubber glove samples in contact with nTiO2 in water. The first analysis showed that nTiO2 solution penetrates some of the materials after prolonged dynamic deformations. These results were partly attributed to modifications in the physical and mechanical properties of protective gloves materials that were induced by repetitive mechanical deformations and/or the presence of the colloidal solution.

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